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Chemical Spill Kits Must Haves by Environmental Science

Spill kits are collection of materials and tools that are required for taking counter measures on oil spills and chemical spills. These kits help in reducing the number of accidents and hazardous diseases whenever chemical or oil spills happen. It is very important to note that specific spill kits are meant for particular tasks and spill kits must be compatible with the spilled chemicals. In other words, precaution should be taken for absorbent material that is used for absorbing acid and must not react. In such cases, only specific acid spill kit should be used otherwise it can cause any type of dangerous accident or could generate additional danger that can increase the hazard level of the spill. Therefore, the selection of the spill kit should be made on the basis of the nature of spilled chemical, location of the spill and volume of the spill. Since many types of kits are available, but chemical spill kits should include the following items:

†Absorbents like sand and saw dust can absorb liquid spills, but absorbent pillows and booms are used for larger spills.
†Sodium hydrogen carbonate can be used for corrosive liquid spills.
†For sweeping up and carrying absorbent materials, brooms, dustpans and open baskets can be used which depletes or reduces manual handling.Spill kits are collection of materials and tools that are required for taking counter measures on oil spills and chemical spills. These kits help in reducing the number of accidents and hazardous diseases whenever chemical or oil spills happen. It is very important to note that specific spill kits are meant for particular tasks and spill kits must be compatible with the spilled chemicals. In other words, precaution should be taken for absorbent material that is used for absorbing acid and must not react. In such cases, only specific acid spill kit should be used otherwise it can cause any type of dangerous accident or could generate additional danger that can increase the hazard level of the spill. Therefore, the selection of the spill kit should be made on the basis of the nature of spilled chemical, location of the spill and volume of the spill. Since many types of kits are available, but chemical spill kits should include the following items:

†Absorbents like sand and saw dust can absorb liquid spills, but absorbent pillows and booms are used for larger spills.
†Sodium hydrogen carbonate can be used for corrosive liquid spills.
†For sweeping up and carrying absorbent materials, brooms, dustpans and open baskets can be used which depletes or reduces manual handling.
†Vermiculite in sufficient quantities is capable of handling chemical container of non corrosive liquid.
†Neutralizer substances that can neutralize the effect of acid, bases and solvent spills.
†Sealed plastic bags for containing spilled oils and chemicals prior to disposal. Plastic drums with lid can also be used for the same purpose as another alternative.
†Personal Protective Equipments (PPE) that includes safety gloves, gas masker, goggles, chemical suit or coat and other protective clothing items and accessories. These protective clothing is meant for better safety and protection of personnel working in laboratories, plants and other areas from chemical spills.
†Items like shovels are used for sweeping or moving absorbent materials from spilled location into plastic bags.
†A pH meter should be a must have item in spill kits. pH meter is an electronic device which is used to measure the acidity or alkalinity (pH levels) of a liquid/ chemical.
†Chemical spill clean-up procedure in a step-by-step detailed version.

There are many websites that offer chemical storage recommendations, laboratory equipments and chemicals for any type of clinical, research or any other work. Accidents caused due to negligence in handling chemicals or chemical spills can be prevented by using flammable storage cabinet. These cabinets are designed in such a way that they prevent chemical liquids from the threat of flames. It is always suggested to buy cabinets which meet the OSHA and NFPA standards and specifications. Many companies offer flammable storage cabinets made from steel and polyethylene material. One can find a number of these cabinets in different styles and features. It is very important to have a spill control system and personal protective equipment for personnel working in laboratories, research centers and other places where chemical handling is done.
†Vermiculite in sufficient quantities is capable of handling chemical container of non corrosive liquid.
†Neutralizer substances that can neutralize the effect of acid, bases and solvent spills.
†Sealed plastic bags for containing spilled oils and chemicals prior to disposal. Plastic drums with lid can also be used for the same purpose as another alternative.
†Personal Protective Equipments (PPE) that includes safety gloves, gas masker, goggles, chemical suit or coat and other protective clothing items and accessories. These protective clothing is meant for better safety and protection of personnel working in laboratories, plants and other areas from chemical spills.
†Items like shovels are used for sweeping or moving absorbent materials from spilled location into plastic bags.
†A pH meter should be a must have item in spill kits. pH meter is an electronic device which is used to measure the acidity or alkalinity (pH levels) of a liquid/ chemical.
†Chemical spill clean-up procedure in a step-by-step detailed version.

There are many websites that offer chemical storage recommendations, laboratory equipments and chemicals for any type of clinical, research or any other work. Accidents caused due to negligence in handling chemicals or chemical spills can be prevented by using flammable storage cabinet. These cabinets are designed in such a way that they prevent chemical liquids from the threat of flames. It is always suggested to buy cabinets which meet the OSHA and NFPA standards and specifications. Many companies offer flammable storage cabinets made from steel and polyethylene material. One can find a number of these cabinets in different styles and features. It is very important to have a spill control system and personal protective equipment for personnel working in laboratories, research centers and other places where chemical handling is done.

Ecospill is an Australian Leading Suppliers of Spill Control Kits and Environmental Safety Equipment like Spill Kits and flammable storage cabinet Products.

Article Source: http://www.earticlesonline.com/Article/Chemical-Spill-Kits-Must-Haves/1193930

what is chemical spill kit?

what are the types of chemical spill kit available.where can i view the photo of these kits and how to use it when chemical spills occur?

Chemical Spill Procedures

Spill Response and Clean-up Procedures
Developing a Spill Response Plan
Recommended Spill Control Materials Inventory
Spill Response and Clean-up Procedures

In the event of a chemical spill, the individual(s) who caused the spill is responsible for prompt and proper clean-up. It is also their responsibility to have spill control and personal protective equipment appropriate for the chemicals being handled readily available. See Developing a Spill Response Plan for more information.

The following are general guidelines to be followed for a chemical spill. More detailed procedures may be available in your Departmental Chemical Hygiene Plan or Spill Response Plan.

Immediately alert area occupants and supervisor, and evacuate the area, if necessary.

If there is a fire or medical attention is needed, contact Public Safety at 911.

Attend to any people who may be contaminated. Contaminated clothing must be removed immediately and the skin flushed with water for no less than fifteen minutes. Clothing must be laundered before reuse. See First Aid for Chemical Exposures for more information.

If a volatile, flammable material is spilled, immediately warn everyone, control sources of ignition and ventilate the area.

Don personal protective equipment, as appropriate to the hazards. Refer to the Material Safety Data Sheet or other references for information.

Consider the need for respiratory protection. The use of a respirator or self-contained breathing apparatus requires specialized training and medical surveillance. Never enter a contaminated atmosphere without protection or use a respirator without training. If respiratory protection is needed and no trained personnel are available, call EHS at x8-5294 or Public Safety at 911. If respiratory protection is used, be sure there is another person outside the spill area in communication, in case of an emergency. If no one is available, contact Public Safety.

Using the chart below, determine the extent and type of spill. If the spill is large, if there has been a release to the environment or if there is no one knowledgeable about spill clean-up available, contact EHS at x8-5294 or Public Safety at 911.
Category Size Response Treatment Materials
Small up to 300cc chemical treatment or absorption neutralization or absorption spill kit
Medium 300 cc - 5 liters absorption absorption spill kit
Large more than 5 liters call public safety outside help

Protect floor drains or other means for environmental release. Spill socks and absorbents may be placed around drains, as needed.

Contain and clean-up the spill according to the table above.
Loose spill control materials should be distributed over the entire spill area, working from the outside, circling to the inside. This reduces the chance of splash or spread of the spilled chemical. Bulk absorbents and many spill pillows do not work with hydrofluoric acid. POWERSORB (by 3M) products and their equivalent will handle hydrofluoric acid. Specialized hydrofluoric acid kits also are available. Many neutralizers for acids or bases have a color change indicator to show when neutralization is complete.

When spilled materials have been absorbed, use brush and scoop to place materials in an appropriate container. Polyethylene bags may be used for small spills. Five gallon pails or 20 gallon drums with polyethylene liners may be appropriate for larger quantities.

Complete a hazardous waste sticker, identifying the material as Spill Debris involving XYZ Chemical, and affix onto the container. Spill control materials will probably need to be disposed of as hazardous waste. Contact EHS at 258-5294 for advice on storage and packaging for disposal.

Decontaminate the surface where the spill occurred using a mild detergent and water, when appropriate.

Report all spills to your supervisor or the Principal Investigator.

Developing a Spill Response Plan

An effective spill response procedure should consider all of the items listed below. The complexity and detail of the plan will, of course depend upon the physical characteristics and volume of materials being handled, their potential toxicity, and the potential for releases to the environment.

Review Material Safety Data Sheets (MSDSs) or other references for recommended spill cleanup methods and materials, and the need for personal
protective equipment (e.g., respirator, gloves, protective clothing, etc.)

Acquire sufficient quantities and types of appropriate spill control materials to contain any spills that can be reasonably anticipated. The need for equipment to disperse, collect and contain spill control materials (e.g., brushes, scoops, sealable containers, etc.) should also be reviewed. See Recommended Spill Control Materials Inventory for more details.

Acquire recommended personal protective equipment and training in its proper use. For example, if an air purifying respirator or self-contained breathing apparatus are needed, personnel must be enrolled in the Respiratory Protection Program and attend annual training and fit-testing.

Place spill control materials and protective equipment in a readily accessible location within or immediately adjacent to the laboratory.

Develop a spill response plan that includes:

Names and telephone numbers of individuals to be contacted in the event of a spill.

Evacuation plans for the room or building, as appropriate.

Instructions for containing the spilled material, including potential releases to the environment (e.g., protect floor drains).

Inventory of spill control materials and personal protective equipment.

Means for proper disposal of cleanup materials (in most cases, as hazardous waste) including contaminated tools and clothing.

Decontamination of the area following the cleanup.

Discuss the spill response plans with all employees in the area. EHS offers training for employees who work directly with chemicals (see Chemical Spills and Waste Procedures) and who are expected to respond outside their work area to assist with spill cleanup (see Chemical Emergency Response (HAZWOPER) First Responder - Operations Level Training). Contact Robin Izzo at 258-6259 to schedule a session for your area.
Recommended Spill Control Material Inventory

Your laboratory or work area should have access to sufficient quantity of absorbents or other types of materials to control any spill that can be reasonably anticipated. Vermiculite, lined 5-gallon pails and limited spill control materials are available at the loading docks of Lewis Thomas Lab, Frick, and E-Quad. Additional materials may be found in certain laboratories and the chemical stockrooms.

Personal Protective Equipment

2 pairs chemical splash goggles

2 pairs of gloves (recommend Silver Shield or 4H)

2 pairs of shoe covers

2 plastic or Tyvek aprons and/or Tyvek suits
Absorption Materials

4 3M POWERSORB spill pillows (or equivalent)

1 3M POWERSORB spill sock

2 DOT pails (5 gallon) with polyethylene liners

1 filled with loose absorbent, such as vermiculite or clay

1 with minimum amount of loose absorbent in the bottom
Neutralizing Materials

Acid Neutralizer

Caustic Neutralizer

commercial neutralizers, such as Neutrasorb (for acids) and Neutracit-2 (for bases) have built in color change to indicate complete neutralization

Solvent Neutralizer

commercial solvent neutralizers, such as Solusorb, act to reduce vapors and raise the flashpoint of the mixture
Mercury Spills

Small mercury vacuum to pick up large drops (optional)

Hg Absorb Sponges - amalgamate mercury residue

Hg Absorb Powder - amalgamates mercury

Hg Vapor Absorbent - reduces concentration of vapor in hard to reach areas

Mercury Indicator - powder identifies presence of mercury
Clean-up Tools

Polypropylene scoop or dust pan

Broom or brush with polypropylene bristles

2 polypropylene bags

sealing tape

pH test papers

waste stickers

floor sign - DANGER Chemical Spill - Keep Away

The pictures at www.udel.edu/OHS/chemspillkit/chemspillkit.html or images.google.com

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This entry was posted on Thursday, April 1st, 2010 at 1:58 am and is filed under Medical, Mobility and Special Needs. You can follow any responses to this entry through the RSS 2.0 feed. Both comments and pings are currently closed.